Intercalation of primary alkylamines into lambda-zirconium phosphate: lambda-type materials with extended interlayer separation

摘要

The intercalation of primary alkylamine into Zirconium phosphate (ZrP) is very powerful synthetic tool to facilitate the diffusion and incorporation of huge organic and inorganic molecules inside the interlayer gallery of ZrP. The intercalation of primary alkylamine into alpha- and gamma-type ZrP is well studied. However, the intercalation chemistry of lambda-ZrP has never been investigated until now. It has been found that lambda-type materials with extended interlayer separation can be obtained by intercalation of primary alkylamines (CnH2n+1NH2; n = 1, 2, 4 and 6) into the interlayer gallery of lambda-ZrP.