Evidence of an dlimination mechanism in thermal decomposition of hexahydro-1,3,5-trinitro-1,3,5-trizine and related compounds under high pressure in solution

摘要

The thermal decomposition of a number of six-membered cyclic nitramines and nitrosamines was studied under pressures up to 1.1 Gpa in dilute solution (THF). The studied nitramines and nitrosamines include hexahydro-1,3,5-trinitrol-1,3,3,5,5-pentanitropiperidine, and trinitropyrimidine, hexahydro-1,3,5,-tetraitropyrimidine, 1,3,3,5,5-pentanitropiperidine, and hexahydro-1,3,5-trinitroso-1,3,5-triazine (TRDX).