Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent

Xu W; Dolbier WR

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Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent

机译：使用CF3I / TDAE试剂实现亚胺的亲核三氟甲基化

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The nucleophilic trifluoromethylation reagent derived from CF3I and tetrakis(dimethylamino)ethylene (TDAE) was found to be effective in addition to both N-tosyl aldimines and N-tolyl sulfinimines, the latter reaction exhibiting very good diastereoselectivity.

机译：已发现，除N-甲苯磺酰基亚胺和N-甲苯磺酰亚胺之外，衍生自CF3I和四（二甲基氨基）乙烯（TDAE）的亲核三氟甲基化试剂也是有效的，后者反应表现出非常好的非对映选择性。

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来源
《The Journal of Organic Chemistry》 |2005年第12期|p. 4741-4745|共5页
作者
Xu W; Dolbier WR;
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作者单位

Univ Florida, Dept Chem, Gainesville, FL 32611 USA;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
ASYMMETRIC-SYNTHESIS; AMINES; ALDIMINES; FLUORINE; KETONES; DESIGN; AMIDES; AGENTS;

机译：不对称合成;胺;醛亚胺;氟;酮;设计;酰胺;试剂;
入库时间 2022-08-18 00:03:11

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3. New stable reagents for the nucleophilic trifluoromethylation. Part 4: Trifluoromethylation of disulfides and diselenides with hemiaminals of trifluoroacetaldehyde [J] . G.Blond, B.R.Langlois Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第13期

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4. Nucleophilic and Electrophilic Fluorination and Trifluoromethylation of Organic Compounds [C] . Jeanne M. Shreeve Sino-Japan Conference of Fluorochemical Engineering amp; Fine Chemicals(FChina2001); 20010522-26; Xi'an(CN) . 2001

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Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent

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