Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles

Xurong Qin; Boya Feng; Jiaxing Dong; Xiaoyu Li; Ying Xue; Jingbo Lan; and Jingsong You

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Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles

机译：铜（II）催化的两个唑之间的脱氢交叉偶联

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摘要

The copper(II)-catalyzed dehydrogenative coupling between two different azoles for the preparation of unsymmetrical biazoles has been developed. The current catalytic system can effectively control the chemoselectivity for heterocoupling over homocoupling.

机译：已经开发出了铜（II）催化的两种不同的唑之间的脱氢偶联反应，用于制备不对称的联唑。当前的催化系统可以有效地控制用于异质偶联的化学选择性。

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来源
《The Journal of Organic Chemistry》 |2012年第17期|7677-7683|共7页
作者
Xurong Qin; Boya Feng; Jiaxing Dong; Xiaoyu Li; Ying Xue; Jingbo Lan; and Jingsong You;
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作者单位

Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry and State Key Laboratory of Biotherapy West China Hospital West China Medical School Sichuan University 29 Wangjiang Road Chengdu 610064 P. R. China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
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入库时间 2022-08-17 13:29:39

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专利

1. Copper(II)-catalyzed dehydrogenative cross-coupling between two azoles [J] . Qin X., Feng B., Dong J., The Journal of Organic Chemistry . 2012,第17期

机译：铜（II）催化的两个唑之间的脱氢交叉偶联
2. Cu-Catalyzed Direct C-P Bond Formation through Dehydrogenative Cross-Coupling Reactions between Azoles and Dialkyl Phosphites [J] . Hore Soumyadip, Srivastava Abhijeet, Singh Ravi P. The Journal of Organic Chemistry . 2019,第11期

机译：Cu催化的直接C-P键形成通过氮孔和二烷基磷酸酯之间的脱氢交联反应形成
3. Palladium-Catalyzed Dehydrogenative Cross-Couplings of Benzazoleswith Azoles [J] . Wei Han, Peter Mayer, Armin R. Ofial Angewandte Chemie . 2011,第9期

机译：钯催化的苯并唑与唑类的脱氢交叉偶联
4. Nanocopper-Catalyzed Cross-Coupling Reaction for the Synthesis of Diarylethers [C] . Duangruthai Phithak, Siripong Sremethean, Jakkrapan Arjsalee International Conference on Chemistry and Chemical Process . 2012

机译：纳米泊醇催化的交叉偶联反应，用于合成二芳酯
5. I. Heterogeneous cross-coupling reactions catalyzed by nickel-in-charcoal and copper-in-charcoal. II. Asymmetric 1,2/1,4-reductions catalyzed by copper hydride. III. Atropselective synthesis of the biaryl A-B ring system of vancomycin utilizing an internally tethered, nonracemic ligand. [D] . Lee, Ching-Tien. 2009

机译：I.炭中镍和炭中铜催化的非均相交叉偶联反应。二。氢化铜催化的不对称1,2 / 1,4-还原反应。三，利用内部束缚的非外消旋配体进行万古霉素联芳基A-B环系统的选择性催化合成。
6. Ni-Catalyzed Dehydrogenative Cross-Coupling: Direct Transformation of Aldehydes to Esters and Amides [O] . Dr. Aaron M. Whittaker, Dr. Vy M. Dong -1

机译：镍催化的脱氢交叉偶联：醛直接转化为酯和酰胺
7. Cu-Catalyzed Direct CP Bond Formation through Dehydrogenative Cross-Coupling Reactions between Azoles and Dialkyl Phosphites [O] . -1

机译：通过氮孔和二烷基磷酸酯之间的脱氢交叉偶联反应，Cu催化的直接Cp键形成

Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles

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