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Thermal degradation of polyethylene oxide blended with novolac type phenolic resin

机译:酚醛清漆型酚醛树脂与聚环氧乙烷的热降解

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摘要

The miscibility and thermal degradation of poly(ethylene oxide) (PEO) toughened novolac type phenolic resin were investigated. Differential scanning calorimetry (DSC) results confirmed that phenolic resin/PEO blend was blended completely. Infrared spectra show that hydrogen bonding existed in the blends. Thermal degradation of poly(ethylene oxide) blended with novolac type phenolic resin has been studied utilizing a dynamic thermogravimetric technique in a flowing nitrogen atmosphere at several heating rates (i.e. 5, 10, 20, 40°C/min). Thermal degradation of phenolic resin/PEO blends takes place in multiple steps. Chemical structure and components of blends affected thermal degradation, which coincided with the data from thermal degradation of novolac type phenolic resin/PEO blends by thermogravimetric analysis (TGA).
机译:研究了聚环氧乙烷(PEO)增韧酚醛清漆型酚醛树脂的混溶性和热降解性。差示扫描量热法(DSC)结果证实酚醛树脂/ PEO共混物完全共混。红外光谱表明共混物中存在氢键。用动态热重技术在流动的氮气气氛中以几种加热速率(即5、10、20、40℃/ min)研究了与酚醛清漆型酚醛树脂共混的聚环氧乙烷的热降解。酚醛树脂/ PEO共混物的热降解过程分多个步骤进行。共混物的化学结构和成分会影响热降解,这与酚醛清漆型酚醛树脂/ PEO共混物通过热重分析(TGA)的热降解数据相吻合。

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  • 来源
    《Journal of Materials Science 》 |2001年第4期| 943-947| 共5页
  • 作者单位

    Department of Chemical Engineering National Tsing-Hua University;

    Department of Chemical Engineering National Tsing-Hua University;

    Department of Chemical Engineering National Tsing-Hua University;

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