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Development of epoxy-based electrets

机译:环氧树脂基驻极体的开发

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The use of a diepoxide resin in the form of 1,4-butanediol diglycidyl ether as the epoxy resin, lithium perchlorate (20 wt.%) as the ionic salt, a hardener (4,7,10-trioxatridecane-1,13-diamine, 15 wt.%) as the curing agent, and a poling DC electric field of 720 V/m gives an electret that exhibits a maximum voltage of 3.4 V during poling (30 min) and a stabilized voltage of 0.67 V after depoling (7.0 h). An epoxy system that hardens slowly (such as one with less hardener) is preferred, due to the longer time during poling for the ions to remain mobile. The rate of hardening rather than that of curing is the governing factor. The lithium salt hastens the curing, but it provides the ions and stabilizes the electret voltage, particularly during the first 30 min of depoling. After the first 30 min of depoling, crosslinking significantly enhances the stability of the electret voltage. The time constant for depoling is 0.8 h during the first 30 min of depoling and is 9 h afterward. Decrease of the lithium salt proportion from 20 to 10 wt.% still provides an effective electret, although the performance is reduced. An epoxy resin produced from Bisphenol F and epichlorohydrin is ineffective due to the high viscosity and fast hardening.
机译:使用1,4-丁二醇二缩水甘油醚形式的双环氧化物树脂作为环氧树脂,高氯酸锂(20 wt。%)作为离子盐,硬化剂(4,7,10-三氧杂环丁烷1,13-二胺(15 wt。%)作为固化剂,极化直流电场为720 V / m,驻极体在极化(30分钟)期间显示最大电压为3.4 V,极化后显示0.67 V的稳定电压( 7.0小时)。最好缓慢固化的环氧体系(例如固化剂较少的环氧树脂),因为在极化过程中需要更长的时间使离子保持可移动。决定性因素是硬化速率而不是固化速率。锂盐可以加快固化速度,但是它可以提供离子并稳定驻极体电压,尤其是在极化的前30分钟。去极化的最初30分钟后,交联会显着提高驻极体电压的稳定性。在开始的前30分钟内,进行轮询的时间常数为0.8 h,之后为9 h。尽管性能降低,但是锂盐比例从20wt。%降低到10wt。%仍然提供有效的驻极体。由双酚F和表氯醇生产的环氧树脂由于粘度高且固化快而无效。

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