Characterization of catalysts obtained from rapidly quenched alloy precursors by electrochemical/chemical processes of material degradation—selected examples

摘要

Rapidly quenched amorphous alloys—containing metallic or metalloid elements—are precursors for selective catalysts of many technically important reactions. To increase their activity, various methods of material degradation occurring at the surface and in the bulk of the rapidly quenched alloys have been used for promoting the catalytic performance of such materials. The modifications of the structure, composition, and morphology of the substrate proved to be efficient in transforming inactive metal alloy precursors into active and selective catalysts for hydrogenation, and dehydrogenation of organic compounds, as well as for other processes like steam reforming of methanol. This article presents several examples of characterization of such catalysts and discusses their selectivity and activity in a connection with physical and chemical properties of their surfaces. Moreover, it is shown that scanning electron microscopy, Auger electron spectroscopy, scanning Auger microscopy, and energy dispersive spectrometry allowed the local changes occurring during the activation process to be identified and their implications for catalytic function to be considered.