A facile preparation of ZnFe_2O_4-CuO-N/B/RGO and ZnFe_2O_4-CuO-C_3N_4 ternary heterojunction nanophotocatalyst: characterization, biocompatibility, photo-Fenton-like degradation of MO and magnetic properties

摘要

To improve the low photocatalytic efficiency, powerful UV light activation, and facile electron transport of ZnFe_2O_4-CuO the combination of different C_3N_4 and N/B/RGO nanosheets in ZnFe_2O_4-CuO-C_3N_4 and ZnFe_2O_4-CuO-N/B/RGO ternary nanoheterojunction fabricated that lead to decrease recombination of electron/hole pairs and high photocatalytic efficiency for degradation of MO organic pollutants. The ZnFe_2O_4, ZnFe_2O_4-N/B/RGO, CuO-N/B/RGO, ZnFe_2. O_4-CuO, ZnFe_2O_4-CuO-N/RGO, ZnFe_2O_4-CuO-B/RGO, ZnFe_2O_4-CuO-RGO, ZnFe_2O_4-CuO-N/B/RGO and ZnFe_2O_4-CuO-C_3N_4 photocatalysts were fabricated by sol-gel technique using melamine, zinc nitrate, ferric nitrate and copper nitrate hexahydrate as precursors. The prepared ZnFe_2O_4-CuO-C_3N_4 photocatalysts have a narrower bandgap than that of ZnFe_2O_4-CuO-N/B/RGO ternary heterojunction, resulting in higher photocatalytic activity for Fenton-type photodecomposition of methyl orange (MO). The activity of the compounds as a photocatalyst can be attributed to an electron transfer process on the surface of the photocatalyst, where the ZnFe_2O_4-CuO-C_3N_4 is a powerful electron donor and electron acceptor for the oxidized MO under ultra-violet (UV) light irradiation. ZnFe_2O_4-CuO-C_3N_4 ternary heterojunction photocatalyst show a red shift (lowest bandgap) in absorption and excellent photocatalytic degradation of MO. The particle sizes of ZnFe_2O_4 and CuO nanoparticles (NPs) were in the ranges of ～650-750 and ～50-150 nm, respectively. The CuO and ZnFe_2O_4 samples were displayed spherical and cubic morphology in FESEM images, respectively. Among the as-prepared nanostructures ZnFe_2O_4-CuO-C_3N_4 show the highest photocatalytic activity and eliminate 95.84% (80 min) of methyl orange under UV light irradiation.