Tunable and white up-conversion emission from Tm~(3+)-Ho~(3+)-Yb~(3+)/-Nd~(3+) co-doped GdVO_4 phosphors under 808-nm excitation

摘要

Lanthanide-doped system with adjustable multicolor and white up-conversion (UC) emission has been developed in GdVO_4 (GVO): Tm~(3+)-Ho~(3+)-Yb~(3+)/-Nd~(3+) phosphors, which are fabricated via a facile solid-state reaction. Herein, we study their phase structures and the Ho~(3+) concentration effect on their up-conversion emission. Under 980 nm excitation, the Tm~(3+)-Ho~(3+)-Yb~(3+) tri-doped GVO phosphors exhibit intense luminescence combined with red, green and blue (RGB) emission and the successive energy transfer between Tm~(3+)-Ho~(3+)-Yb~(3+) ions causes a slight shift in the color coordinates of samples with different doping concentrations. Under 808 nm excitation, the color coordinate of the optimum GVO: Tm~(3+)-Ho~(3+)-Yb~(3+)-Nd~(3+) phosphor is located at (0.3277, 0.3433), which is closest to the ideal white light emission corresponding to (0.3333, 0.3333). Therefore, it is proved that these phosphors provide potential applications in the fields of displays, lasers and optical telecommunication.