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Synthesis and characterization of Fe_2TiO_5 nanoparticles through a sol-gel method and its photocatalyst applications

机译:Fe_2TiO_5纳米粒子的溶胶-凝胶法合成,表征及其光催化应用

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摘要

A novel modified sol-gel method was used in order to synthesize of Fe_2TiO_5 nanoparticles with aid of Fe(NO_3)_3·9H_2O and Ti(OC_3H_7)_4 as the starting reagents in the presence of ethanol as the solvent. To the best of author knowledge, it is first time that oxalic acid was used as a chilate agent in produce Fe_2TiO_5 nanoparticles. Besides, to examine the effect of different surfactants such as oleic acid, oleylamine, sodium dodecyl sulfate and cetyltrimethylammonium bromide on the particle size of final products several tests were performed. The as-synthesized Fe_2TiO_5 nanoparticle was utilized as photocatalyst for decolorisation of Rhodamine-B (RhB) and Methylen blue (MB) to investigate its light harvesting application. The photocatalyst results reveal that the maximum decol-orization of 93 and 95 % for RhB and MB occurred with Fe_2TiO_5 nanoparticle catalyst in 40 min of reaction time under ultraviolet light irradiation, respectively.
机译:为了利用Fe(NO_3)_3·9H_2O和Ti(OC_3H_7)_4作为起始试剂,在乙醇为溶剂的条件下,采用新颖的溶胶-凝胶法合成Fe_2TiO_5纳米粒子。据作者所知,草酸首次用作生产Fe_2TiO_5纳米粒子的螯合剂。此外,为了检验不同表面活性剂(例如油酸,油胺,十二烷基硫酸钠和十六烷基三甲基溴化铵)对最终产品粒径的影响,进行了一些测试。合成后的Fe_2TiO_5纳米粒子被用作光催化剂,用于罗丹明B(RhB)和亚甲基蓝(MB)的脱色,以研究其光收集应用。光催化剂的结果表明,Fe_2TiO_5纳米颗粒催化剂在紫外线照射下的40分钟内,RhB和MB的最大脱色率分别为93%和95%。

著录项

  • 来源
    《Journal of materials science》 |2015年第6期|3957-3962|共6页
  • 作者单位

    Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran;

    Young Researchers and Elites Club, Arak Branch, Islamic Azad University, Arak, Iran;

    Central laboratory, Shazand oil refinery, Arak, Iran;

    Young Researchers and Elites Club, Arak Branch, Islamic Azad University, Arak, Iran;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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