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Construction of CuO/CdS composite nanostructure for photodegradation of pollutants in sewage

机译:CuO / CdS复合纳米结构的光降解污水中污染物的构建

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摘要

The composite of semiconductor photocatalytic materials can effectively improve the solar energy utilization efficiency and quantum efficiency. Therefore, composite semiconductor materials have gradually become one of the most promising photocatalyst for solving water pollution problems. In this work, CuO nanowire arrays were prepared on Cu substrate by a thermal oxidation method, then CuO/CdS composite nanostructure was synthesized through an SILAR technique sequentially. The morphology, micro-area element composition, phase structure and optical properties of CuO/CdS nanostructure were characterized by field emission scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, ultraviolet-visible and photoluminescence spectroscopy respectively. Based on the test results, we systematically discussed the effects of several experimental conditions such as copper substrate, annealing temperature and reaction time on the properties and structure of CuO/CdS composite nanostructure. The resultant binary CuO/CdS composite nanostructure exhibited more excellent photocatalytic activity than pure CuO nanowire arrays both in the photodegradation of simulated contaminant methylene blue (MB) and practical pollutants of sewage.
机译:半导体光催化材料的复合材料可以有效地提高太阳能的利用效率和量子效率。因此,复合半导体材料已逐渐成为解决水污染问题最有希望的光催化剂之一。本工作通过热氧化法在Cu衬底上制备CuO纳米线阵列,然后通过SILAR技术依次合成CuO / CdS复合纳米结构。通过场发射扫描电子显微镜,能量色散光谱,X射线衍射,紫外可见光谱和光致发光光谱分别表征了CuO / CdS纳米结构的形貌,微区元素组成,相结构和光学性质。根据测试结果,我们系统地讨论了铜基片,退火温度和反应时间等多种实验条件对CuO / CdS复合纳米结构的性能和结构的影响。所得的二元CuO / CdS复合纳米结构在模拟污染物亚甲基蓝(MB)和实际污水污染物的光降解方面均比纯CuO纳米线阵列表现出更优异的光催化活性。

著录项

  • 来源
    《Journal of materials science》 |2019年第17期|15989-15999|共11页
  • 作者单位

    China Univ Geosci Fac Mat Sci & Chem Minist Educ Engn Res Ctr Nanogeomat 388 Lumo Rd Wuhan 430074 Hubei Peoples R China;

    China Univ Geosci Fac Mat Sci & Chem Minist Educ Engn Res Ctr Nanogeomat 388 Lumo Rd Wuhan 430074 Hubei Peoples R China|Guangdong Prov Key Lab Soil & Groundwater Pollut 1088 Xueyuan Rd Shenzhen 518055 Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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