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Bismuth titanate nanoparticles dispersed polyacrylates

机译:钛酸铋纳米粒子分散聚丙烯酸酯

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摘要

We successfully dispersed amorphous bismuth titanate nanoparticles (<50 nm) in situ in poly-hydroxy ethyl methacrylate via a sol-gel process. Since less than 20 percent of the polymer composition is bismuth titanate by weight, the material exhibits high refractive indices (>1.6) and good optical transparency (>90 percent transmittance from 530 to 800 nm). Furthermore, this highly cross-linked material has an improved thermal stability and a lower coefficient of thermal expansion than that of neat polymers. The material also displays a high dielectric constant (>10) without ferroelectricity. Thus the material has potential applications in optical lenses, optical waveguides, and capacitors.
机译:我们通过溶胶-凝胶工艺成功地将无定形钛酸铋纳米粒子(<50 nm)原位分散在聚甲基丙烯酸羟乙酯中。由于不到20%的聚合物成分是钛酸铋,因此该材料具有高折射率(> 1.6)和良好的光学透明性(530至800 nm的透射率> 90%)。此外,与纯聚合物相比,这种高度交联的材料具有改善的热稳定性和较低的热膨胀系数。该材料还显示出高介电常数(> 10)而没有铁电。因此,该材料在光学透镜,光波导和电容器中具有潜在的应用。

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