Magnetocaloric properties of the La_(0.7)Pr_(0.3)Fe_(13-x)Si_x compounds

摘要

Magnetic entropy change ΔS_m, hysteresis loss and refrigerant capacity of NaZn_(13)-type La_(0.7)Pr_(0.3)Fe_(13-x)Si_x (1.5≤x≤2.0) compounds have been investigated. The Curie temperature T_C increases linearly with the increase of silicon concentration. Although the maximum value of ΔS_m under a field change of 0-5T decreases from 30.5 to 11.4J/kgK as x increases from 1.5 to 2.0, the hysteresis loss at T_C reduces remarkably from 89.2 J/kg for x = 1.5 to zero for x = 2.0 because the increase of Si content can weaken the itinerant electron metamagnetic transition. The effective refrigerant capacity RC_(eff) is maintained at high values of 362-439 J/kg for a field change of 0-5 T. This implies that a large ΔS_m and a high RC_(eff) can be achieved simultaneously in the La_(0.7)Pr_(0.3)Fe_(13-x)Si_x compounds.