SYNTHESIS AND CHARACTERIZATION OF NEW THERMOTROPIC SIDE-CHAIN LIQUID CRYSTAL POLYMERS CONTAINING 1,6-HEPTADIYNE BACKBONE

摘要

Poly(1,6-heptadiyne) derivatives with side-group liquid crystalline mesogens are prepared by ring-forming metathesis polymerization with transition metal catalysts. MoCl_5-based catalyst systems are more effective for the polymerization of 1,6-heptadiyne monomers with various mesogenic groups than are WCl_6-based catalyst systems. The resulting polymers exhibit good solubility in common organic solvents such as chloroform and THF, and they can be easily spin-coated on ITO glass. The weight-average molecular weights of the polymers are in the 3.5 to 26 x 10~4 range relative to polystyrene standards by GPC. The ~1H-, ~(13)C-NMR, and IR spectra of the resulting polymers indicate that side-chain liquid crystal polymers with a 1,6-heptadiyne backbone possess a polyene structure, presumably with cyclic recurring units in the polymer backbone. Thermal behaviors, morphology, and electrical conductivities are investigated by using differential scanning calorimetry, cross-polarized optical microscopy, and an LCR meter. M-1 and P-1 displayed enantiotropic liquid crystallinity showing reversible phase transition. M-2 and P-2 displayed no mesophase. The electrical conductivities of the film-type polymers are in the 10~(-4) to 10~(-2) S/cm range.