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首页> 外文期刊>日本エネルギ-学会誌 >劣質炭の溶剤改質によるコークス原料化技術
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劣質炭の溶剤改質によるコークス原料化技術

机译:溶剂重整贫煤制焦技术

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摘要

Coke production has become more expensive with the decreasing supply of caking coals, and the degree of technology required to manufacture high-quality coke from low-quality coal. Upgraded coals (called HyperCoal) from such low-rank coals can be produced by thermal extraction technology under mild condition; at temperature of 360 - 400℃, pressure of less than 4 MPa, without catalysts and hydrogen. HyperCoals have high thermoplasticity during heating; in particular, HyperCoals obtained from low-rank coals show high thermoplasticity beginning at temperatures near 150℃. On increasing the extraction temperature for sub-bituminous coal, the softening and the resolidification temperatures shifted to higher temperatures. Nuclear magnetic resonance measurements showed that the ratio of aromatic carbon increased with increasing extraction temperature, indicating that some modification reactions occurred. These results suggest that the HyperCoal obtained at higher temperatures contains more, relatively heavy components. The effects of blending these HyperCoals into standard coal blends were investigated. For coal blends made with the HyperCoal, produced from a sub-bituminous coal, increasing the extraction temperature from 360 to 400℃ increased the thermoplasticity significantly. Furthermore, the addition of 10% HyperCoal, extracted at 400℃, increased the tensile strength of the semicokes.%原油価格が100ドルを超える昨今のエネルギー高騰のrn状況の中,2008年の石炭価格も,発電用石炭が昨年度2.3rn倍の125ドル前後,また鉄鋼向け原料炭の価格に至ってrnは,年初豪州での豪雨による生産の減少と世界的な実需rnの拡大により,昨年に比べて3倍に引き上げられる見通rnしとなり,石炭も石油に続き本格的な“100ドル時代”にrn突入したと見られる。
机译:随着结块煤供应的减少,以及从劣质煤制造高质量焦炭所需的技术水平,焦炭生产变得更加昂贵。可以通过热提取技术在温和的条件下生产此类低品位煤的提质煤(称为HyperCoal)。温度为360-400℃,压力小于4 MPa,无催化剂和氢气。 HyperCoals在加热过程中具有很高的热塑性;特别是从低阶煤获得的HyperCoal在接近150℃的温度下显示出高热塑性。随着亚烟煤提取温度的升高,软化和再凝固温度转移到更高的温度。核磁共振测量表明,芳族碳的比例随提取温度的升高而增加,表明发生了一些修饰反应。这些结果表明,在较高温度下获得的HyperCoal包含更多,相对较重的组分。研究了将这些HyperCoal掺入标准煤掺混物中的效果。对于由次烟煤生产的HyperCoal制成的掺混煤,将提取温度从360℃提高到400℃会显着提高热塑性。此外,添加400%提取的10%的HyperCoal可以提高半焦的抗张强度。が昨年度2.3rn倍の125ドル前后,また鉄钢向け原料炭の価格に至ってrnは,年初豪州での豪雨による生产の减少と世界的な実需rnの拡大により,昨年に比べて3倍に引き上げられる见通rnしとなり,石炭も石油に続き本格的な“ 100ドル时代”にrn突入したと见られる。

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