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A novel approach of preparing TiO_2 films at low temperature and its application in photocatalytic degradation of methyl orange

机译:低温制备TiO_2薄膜的新方法及其在甲基橙光催化降解中的应用

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摘要

Here we introduce a novel approach of preparing TiO_2 films on conductive substrates at low temperature by electrophoretic deposition method without successive calcinate treatment. The photocatalytic activity of the non-calcinated TiO_2 film was evaluated by degradation rate of methyl orange (MO). We found that the degradation rate of MO increased with the amount of TiO_2, and it was higher in both acidic and alkaline media than under neural condition. In addition, lower pH was more favorable for the degradation of MO. The photocatalytic degradation of MO could be described as pseudo-first order reactions. When the initial concentration of MO increased from 1 mg/Lto 10mg/L, the highest degradation rate was achieved at 5 mg/L. The apparent reaction rate constant was calculated to be 0.0098 min~(-1).
机译:在这里,我们介绍了一种通过电泳沉积方法在低温下在导电基材上制备TiO_2薄膜的新颖方法,无需连续煅烧处理。通过甲基橙(MO)的降解速率评价未煅烧的TiO_2薄膜的光催化活性。我们发现,MO的降解速率随TiO_2的增加而增加,在酸性和碱性介质中均高于在神经环境下。另外,较低的pH值更有利于MO的降解。 MO的光催化降解可以描述为伪一级反应。当MO的初始浓度从1 mg / L增加到10mg / L时,最高降解速率为5 mg / L。表观反应速率常数经计算为0.0098min〜(-1)。

著录项

  • 来源
    《Journal of Hazardous Materials 》 |2010年第3期| p.750-754| 共5页
  • 作者单位

    Environmental Science Research Institute, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, PR China;

    rnEnvironmental Science Research Institute, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, PR China;

    rnEnvironmental Science Research Institute, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    non-calcinated TiO_2 film; electrophoretic deposition; photocatalytic activity; methyl orange degradation;

    机译:非煅烧TiO_2膜电泳沉积光催化活性甲基橙降解;

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