Preparation, characterization and adsorption properties of a novel 3-aminopropyltriethoxysilane functionalized sodium alginate porous membrane adsorbent for Cr(III) ions

摘要

In this study, we prepared 3-aminopropyl-triethoxysilane (APTEOS) functionalized sodium alginate (SA) porous membrane adsorbent (APTEOS/SA) and tested its adsorption performance for removing of Cr(III) ions. The physico-chemical properties of the pristine and Cr(III) ions loaded APTEOS/SA were investigated by FT-IR, SEM-EDX, TG, AFM, and contact angle goniometer methods. To investigate the adsorption kinetics of Cr(Ili) ions onto this newly developed APTEOS/SA, we performed a batch of experiments under different adsorption conditions: solution pH, adsorbent dose, initial Cr(III) ion concentration, adsorption temperature, and contact time. The APTEOS/SA exhibited an encouraging uptake capacity of 90.0 mg/g under suitable adsorption conditions. To study the mechanism of adsorption process, we examined the Lagergren pseudo-first-order and pseudo-second-order kinetic model, the intra-particular diffusion model, and the Crank model. Kinetics experiments indicated that the pseudo-first-order model displayed the best correlation with adsorption kinetics data. The Crank model showed that the intra-particle solute diffusion was the main rate-controlling step. Furthermore, our adsorption equilibrium data could be better described by the Freundlich equation. We also carried out consecutive adsorption-desorption experiments eight times to show that the APTEOS/SA has encouragingadsorption-desorption efficiencies. The results indicates that the prepared adsorbent is promising for using as an effective and economical adsorbent for Cr(III) ions removal.