Inductively coupled plasma torch efficiency at atmospheric pressure for organo-chlorine liquid waste removal: Chloroform destruction in oxidative conditions

摘要

The performance of a plasma reactor for the degradation of chlorinated hydrocarbon waste is reported. Chloroform was used as a target for a recently patented destruction process based using an inductive plasma torch. Liquid waste was directly injected axially into the argon plasma with a supplied power of ～4kW in the presence of oxygen as oxidant and carrier gas. Decomposition was performed at CHCl_3 feed rates up to 400 g h~(-1) with different oxygen/waste molar ratios, chloroform destruction was obtained with at least 99% efficiency and the energy efficiency reached 100gkWh~(-1). The conversion end products were identified and assayed by online FTIR spectroscopy (CO_2, HCl and H_2O) and redox titration (Cl_2). Considering phosgene as representative of toxic compounds, only very small quantities of toxics were released (<1 gh~(-1)) even with high waste feed rates. The experimental results were very close to the equilibrium composition predicted by thermodynamic calculations. At the bottom of the reactor, the chlorinated acids were successfully trapped in a scrubber and transformed into mineral salts, hence, only CO_2 and H_2O have been found in the final off-gases composition.