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Effect of domain subdivisions on alloy solidification

机译:域细分对合金凝固的影响

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The sensible heat portion of thermal energy storage (TES) for concentrated solar power (CSP) can be achieved using off-eutectic materials. These materials have the advantage of storing in latent as well as sensible heat through a given temperature range. On the other hand, off-eutectic materials have the disadvantage of possibly experiencing segregation effects, most likely impairing their solidification. During solidification, macrosegregation can occur due to a number of possible causes such as density differences in the solid and liquid portions of the mixture/alloy, flows due to capillary forces, flows due to electromagnetic fields or forced stirring, etc. In some cases, macrosegregation can severely affect solidification. One possible means to limit this segregation is with porous media. In this study, the segregation of an off-eutectic material in a porous medium is studied. Pore sizes and porous medium thermal conductivity are varied, revealing the importance of various mechanisms affecting solidification. Smaller pore sizes and higher porous medium thermal conductivities are shown to improve segregation and solidification.
机译:可以使用非共晶材料来实现集中太阳能(CSP)的热能存储(TES)的显热部分。这些材料具有在给定温度范围内潜热和显热存储的优势。另一方面,非共晶材料的缺点是可能会产生偏析效应,最有可能损害其固化。在固化过程中,由于多种可能的原因而可能发生宏观偏析,例如混合物/合金的固体和液体部分的密度差异,由于毛细作用力引起的流动,由于电磁场引起的流动或强制搅拌等。在某些情况下,宏观偏析会严重影响凝固。限制这种偏析的一种可能方法是使用多孔介质。在这项研究中,研究了非共晶材料在多孔介质中的偏析。孔的大小和多孔介质的导热系数各不相同,这揭示了影响固化的各种机制的重要性。较小的孔径和较高的多孔介质热导率可改善偏析和固化。

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