Investigation of crystallization kinetics of sodium bicarbonate in a continuous stirred tank crystallizer

摘要

In our previous work [J. Crystal Growth 263 (2004) 459]. a supersaturation determination Method using a high-precision densimeter was designed and developed for monitoring sodium bicarbonate supersaturation in the sodium carbonate-bicarbonate system. a two-component Solution ill equilibrium. In the present paper, we apply this method to the study of sodium bicarbonate continuous crystallization. It gives till access to the sodium bicarbonate supersaturation evolution. The sodium bicarbonate supersaturation evolution and their crystallization kinetics obtained in a continuous stirred tank crystallizer are investigated under different operational conditions. such as residence time, initial supersaturation and seeding, The induction time determined by density measurement,, is discussed. Mathematical modeling is used to interpret the supersaturation evolution. It is shown that measuring the density gives satisfying performances for studying the crystallization of a two-component solution in equilibrium, such as the sodium carbonate-bicarbonate system. (c) 2005 Elsevier B.V. All rights reserved.