Syntheses, Structures of Two Rare Earth-Vanadyl Complexes and Highly Selective Fluorescence Detection of Zn2+

摘要

Two rare earth vanadyl complexes incorporating N-(p-benzoic acid methylene)imino dimethylene phosphonic acid, {[Ce(H₂O)₇]₂[V₁₀O₂₈]}·11H₂O (1) and {[Gd(H₂O)₇]₂[V₁₀O₂₈]}·11H₂O (2) were synthesized and characterized by IR spectra, UV-Vis spectra, Fluorescence spectra and single crystal X-ray analysis. In complexes 1 and 2, they are isomorphism, triclinic, space group P-1, V5+ ion for the hexa-coordinate with oxygen constitute [V₁₀O₂₈] 6− cluster, in which oxygen were taken μ1, μ2, μ3, μ6 method of allocation. Ce3+ ion is nine-coordinate. Complex 1 has a very strong selective of Zn2+ from the fluorescence spectra, and can as highly selective probes for Zn2+.