A New Glycosylation Method Based on 8-Quinolyl Glycosides

Chih-Wei Chang; Tse-Lok Ho

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A New Glycosylation Method Based on 8-Quinolyl Glycosides

机译：基于8-喹啉糖苷的糖基化新方法

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摘要

A synthesis of two 8-quinolyl glycosides (1a, 2a) and demonstration of their service as glycosyl donors are described. These stable compounds react with various alcohols in the presence of metal salts at 60℃ for 16-48 h to furnish the coupling products in excellent yields (88-96%).

机译：描述了两个8-喹啉基糖苷（1a，2a）的合成及其作为糖基供体的作用。这些稳定的化合物在金属盐存在下于60℃与各种醇反应16-48小时，以极好的收率（88-96％）提供偶联产物。

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来源
《Journal of the Chinese Chemical Society》 |2006年第6期|p.1567-1570|共4页
作者
Chih-Wei Chang; Tse-Lok Ho;
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作者单位

Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, R.O.C.;

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原文格式 PDF
正文语种 eng
中图分类化学;化学工业;
关键词
glycosylation; 8-quinolyl glycosides; metal activation;

机译：糖基化;8-喹啉基糖苷;金属活化;

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专利

1. A New Glycosylation Method Based on 8-Quinolyl Glycosides [J] . Chih-Wei Chang, Tse-Lok Ho Journal of the Chinese Chemical Society. . 2006,第6期

机译：基于8-喹啉糖苷的糖基化新方法
2. Efficient glycosylation using ODS adsorption method based on the affinity of long alkoxybenzyl glycoside [J] . Imagawa H, Kinoshita A, Yamamoto H, Synlett . 2008,第13期

机译：基于长烷氧基苄基糖苷亲和力的ODS吸附法进行高效糖基化
3. (2-Ketulosonyl)onate 2,3-O-thionocarbonate donors for the synthesis of KO and KDO alpha-glycosides and a one-pot glycosylation method for 2-keto acid donors [J] . Mong Kwok-Kong Tony, Pradhan Tapan Kumar, Chiu Cheng-Hsin, Organic Chemistry Frontiers . 2020,第16期

机译：（2-酮烷基）在2,3-酮碳酸酯供体上用于合成KO和KDOα-糖苷和2-酮酸供体的单壶糖基化方法
4. Synthesis of the Novel Thienopyrimidine-based S-Glycoside Analogues via Nucleophilic Addition/Cyclization/Glycosylation Reactions [C] . Qiuhong Dai, Kun Zou, Mingguo Liu, International Conference on Chemical Engineering and Advanced Materials . 2013

机译：通过亲核加成/环化/糖基化反应合成新型噻吩基嘧啶的S-糖苷类似物
5. Development of novel glycosylation methodology for convergent oligosaccharide synthesis based on S-thiazolinyl glycosides [D] . Pornsuriyasak, Papapida 2006

机译：基于S-噻唑啉基糖苷的融合寡糖合成新糖基化方法的开发
6. Structures of Some Novel α-Glucosyl Diterpene Glycosides from the Glycosylation of Steviol Glycosides [O] . Indra Prakash, Venkata Sai Prakash Chaturvedula 2014

机译：从甜菊醇糖苷的糖基化反应中一些新型的α-葡萄糖基二萜糖苷的结构
7. A New Glycosylation Method Based on 8-Quinolyl Glycosides [O] . Chih-wei Chang, Tse-lok Ho 2015

机译：一种新的基于8-喹啉糖苷的糖基化方法

A New Glycosylation Method Based on 8-Quinolyl Glycosides

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