Kinetics of hydrogen adsorption and desorption on Si(100) surfaces

摘要

The kinetics of molecular hydrogen reactions at the Si (100) surface has been studied by simulation to extract the physics underlying two unexpected experimental observations: apparently first-order desorption kinetics and an increase in sticking probability with hydrogen coverage. At a partially H-terminated Si(100) surface, each Si dimer assumes an unoccupied dimer (UOD), singly occupied dimer (SOD), or doubly occupied dimer (DOD) structure. In our hydrogen reaction model based on an inter-dimer mechanism, a site consisting of an adjacent pair of a DOD and a UOD (DOD/UOD) is a key component for the desorption and adsorption kinetics of hydrogen at the Si(100) surface. To simulate reaction kinetics of both reactions, DU (D: DOD, U: UOD) and SS (S: SOD) pathways are proposed: DU pathway claims that the adsorption as well as desorption of hydrogen takes place at common sites having a cw-configured SOD/SOD pair that is transformed transiently from a DOD/ UOD pair by H(D) diffusion. Thus the adsorption obeys the so-called 4H mechanism, but the desorption obeys the 2H mechanism. SS pathway claims that the adsorption occurs at sites having a UOD/UOD pair, and the desorption occurs at sites having a ris-configured SOD/SOD pair that is generated by diffusion of isolated SODs. To simulate temperature-programmed-desorption spectra and sticking probability vs coverage curves, thermo-statistics for a lattice-gas system characterized with parameters for hydrogen pairing and dimer clustering is used to evaluate equilibrium populations of DOD/UOD pairs and isolated SODs. The model simulation based on the above reaction model successfully reproduces all of the complicated, coverage dependent adsorption and desorption reactions of hydrogen at Si(100) surfaces. Specifically, at high coverage above 0.1 ML majority of the adsorption and desorption proceed along the DU pathway. Hence, it is suggested that the adsorption and desorption in the high coverage regime are not microscopically reversible. On the other hand, at low coverages below 0.1 ML, the simulation shows up that the majority of adsorption proceeds along the SS pathway, and the desorption by the DU pathway. Since both reactions obey the 2H mechanism, it is suggested that the desorption and adsorption in the low coverage regime are microscopically reversible.