Properties of K,Rb-intercalated C_(60) encapsulated inside carbon nanotubes called peapods derived from nuclear magnetic resonance

摘要

We present a detailed experimental study on how magnetic and electronic properties of Rb,K-intercalated C_(60) encapsulated inside carbon nanotubes called peapods can be derived from ~(13)C nuclear magnetic resonance investigations. Ring currents do play a basic role in those systems; in particular, the inner cavities of nanotubes offer an ideal environment to investigate the magnetism at the nanoscale. We report the largest diamagnetic shifts down to -68.3 ppm ever observed in carbon allotropes, which is connected to the enhancement of the aromaticity of the nanotube envelope upon intercalation. The metallization of intercalated peapods is evidenced from the chemical shift anisotropy and spin-lattice relaxation (T_1) measurements. The observed relaxation curves signal a three-component model with two slow and one fast relaxing components. We assigned the fast component to the unpaired electrons charged C_(60) that show a phase transition near 100 K. The two slow components can be rationalized by the two types of charged C_(60) at two different positions with a linear regime following Korringa behavior, which is typical for metallic system and allow us to estimate the density of sate at Fermi level n(E_F).