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A nanocomposite of graphene/MnO2 nanoplatelets for high-capacity lithium storage

机译:纳米石墨烯/ MnO2 纳米复合材料用于高容量锂存储

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摘要

A nanocomposite of graphene/MnO2 nanoplatelets was prepared by one-step chemistry route at room temperature. The microstructure was characterized by X-ray diffraction, N2 absorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Both TEM and SEM images show that MnO2 nanoplatelets are homogeneously distributed on the graphene nanosheets. The electrochemical properties were tested by cyclic voltammetry, galvanostatic charge–discharge experiments. The nanocomposite exhibited high lithium capacity (905 mAh g−1 at 100 mA g−1). The superior lithium storage capability can be attributed to the “open” structure: the large effective surface area and short diffusion paths.
机译:通过一步法在室温下制备了石墨烯/ MnO2 纳米片的纳米复合材料。通过X射线衍射,N2吸收,扫描电子显微镜(SEM)和透射电子显微镜(TEM)对显微组织进行了表征。 TEM和SEM图像均表明,MnO2 纳米片晶均匀分布在石墨烯纳米片上。通过循环伏安法,恒电流充放电实验测试了电化学性能。纳米复合材料显示出高锂容量(在100 mA g-1 下为905 mAh g-1 )。优异的锂存储能力可归因于“开放”结构:大的有效表面积和短的扩散路径。

著录项

  • 来源
    《Journal of Applied Electrochemistry》 |2012年第12期|p.1065-1070|共6页
  • 作者单位

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

    School of Materials Science and Engineering, Chongqing University, Chongqing, 400045, People’s Republic of China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    MnO2; Graphene nanosheets; Lithium ion batteries;

    机译:MnO2;石墨烯纳米片;锂离子电池;

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