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The structural development of zeolite-templated carbon under pyrolysis

机译:热解下沸石模板碳的结构发展

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摘要

Three activated carbon samples were synthesized via the pyrolysis of furfuryl alcohol (FA) impregnated in the porous framework of zeolite Y. The pyrolysis temperature was set at 900, 1050, and 1150 ℃, respectively, to investigate its role on structural development. The surface properties of the carbon samples were characterized using XRD, SEM, Raman, and gas adsorption technologies. It is found that a low pyrolysis temperature is in favor of the structural regularity and the formation of small micropores (d< 1.0 nm), while a high temperature is necessary for the surface area/pore enhancement. However, a too high temperature will result in the collapse of micropores and the formation of mesopores.
机译:通过浸渍在沸石Y多孔骨架中的糠醇(FA)的热解,合成了三个活性炭样品。热解温度分别设定为900、1050和1150℃,以研究其对结构发展的作用。使用XRD,SEM,拉曼和气体吸附技术对碳样品的表面特性进行了表征。发现低的热解温度有利于结构规则性和小的微孔(d <1.0nm)的形成,而高温对于表面积/孔增强是必需的。然而,太高的温度将导致微孔的破裂和中孔的形成。

著录项

  • 来源
    《Journal of Analytical & Applied Pyrolysis》 |2013年第3期|153-157|共5页
  • 作者

    X.H. Song; R. Xu; K. Wang;

  • 作者单位

    School of Chemical & Biomedical Engineering, Nanyang Technological University. Singapore 637459, Singapore;

    School of Chemical & Biomedical Engineering, Nanyang Technological University. Singapore 637459, Singapore;

    Department of Chemical Engineering, The Petroleum Institute, Abu Dhabi, United Arab Emirates;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    activated carbon; template synthesis; zeolite; pyrolysis; adsorption; pore size distribution;

    机译:活性炭;模板合成;沸石热解吸附孔径分布;

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