Solid State Electrochemically Generated Luminescence Based on Serial Frozen Concentration Gradients of Ru~Ⅲ/Ⅱ and Ru~Ⅱ/I Couples in a Molten Ruthenium 2,2'-Bipyridine Complex

Karolyn M. Maness; Hitoshi Masui; R. Mark Wightman

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Solid State Electrochemically Generated Luminescence Based on Serial Frozen Concentration Gradients of Ru~Ⅲ/Ⅱ and Ru~Ⅱ/I Couples in a Molten Ruthenium 2,2'-Bipyridine Complex

机译：基于熔融钌2,2'-联吡啶配合物中Ru〜Ⅲ/Ⅱ和Ru〜Ⅱ/ I对的系列冷冻浓度梯度的固态电化学发光

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The attachment of two polyethylene glycol tails (n=7, MW=350)to ruthenium tris (bipyridine) via ester links on the 4, 4'-positions of one of the bipyridine ligands yields a highly viscous (η≈10~7 cP) molten salt (abbreviated[Ru(bpy)_2(bpy(CO_2MePEG350)_2)](ClO_4)_2) that glasses at ca.-5 deg C.

机译：通过联吡啶配体之一的4、4'-位置上的酯键将两个聚乙二醇尾巴（n = 7，MW = 350）连接到三联钌（联吡啶）产生高粘度（η≈10〜7 cP ）熔融盐（缩写为[Ru（bpy）_2（bpy（CO_2MePEG350）_2）]（ClO_4）_2）在大约-5摄氏度下成玻璃。

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《Journal of the American Chemical Society》 |1997年第17期|p.3987-3993|共7页
作者
Karolyn M. Maness; Hitoshi Masui; R. Mark Wightman;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
中图分类化学;
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入库时间 2022-08-18 01:08:36

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Solid State Electrochemically Generated Luminescence Based on Serial Frozen Concentration Gradients of Ru~Ⅲ/Ⅱ and Ru~Ⅱ/I Couples in a Molten Ruthenium 2,2'-Bipyridine Complex

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