Probing the Factors That Stabilize Mononuclear Rhodium(Ⅱ) Bis(phosphine), η~6-Arene Complexes with Piano-Stool Geometries

摘要

The synthesis, characterization, and electrochemistry of a series of Rh(I) bis(phosphine), η~6-arene, piano- stool complexes are reported. The study reported herein elucidates several of the important factors which lead to the stabilization of Rh(Ⅱ) in this coordination environment.