Enantioselective epoxidation of ω-bromo-2-methyl-1-alkenes catalyzed by chloroperoxidase. Effect of chain length on selectivity and efficiency

摘要

A question that remains is whether admission to the active site or the activation energy for epoxidation represents the higher energy barrier. Further research is expected to proceed involv- ing reaction kinetic experiments, molecular modeling, and random and site-directed mutagenisis.