Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry

Patrick G. Campbell† Eric R. Abbey† Doinita Neiner‡ Daniel J. Grant§ David A. Dixon§ and Shih-Yuan Liu†

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Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry

机译：1,2-氮杂硼烷的共振稳定能：反应量热法的定量实验研究

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Aromatic and single-olefin six-membered BN heterocycles were synthesized, and the heats of hydrogenation were measured calorimetrically. A comparison of the hydrogenation enthalpies of these compounds revealed that 1,2-azaborines have a resonance stabilization energy of 16.6 ± 1.3 kcal/mol, in good agreement with calculated values.

机译：合成了芳香和单烯烃六元BN杂环，并量热测量了氢化热。这些化合物的氢化焓的比较显示，1,2-氮杂萘胺的共振稳定能为16.6±1.3 kcal / mol，与计算值非常吻合。

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《American Chemical Society》 |2010年第51期|p.18048-18050|共3页
作者
Patrick G. Campbell† Eric R. Abbey† Doinita Neiner‡ Daniel J. Grant§ David A. Dixon§ and Shih-Yuan Liu†;
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Department of Chemistry, University of Oregon, Eugene, Oregon 97403, United States, Fundamental Science Division, Pacific Northwest National Laboratory, Richland, Washington 99352, United States, and Department of Chemistry, Shelby Hall, The University of Alabama, Tuscaloosa, Alabama 35487, United States;

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1. Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry [J] . Patrick G. Campbell, Eric R. Abbey, Doinita Neiner, Journal of the American Chemical Society . 2010,第51期

机译：1,2-氮杂硼烷的共振稳定能：反应量热法的定量实验研究
2. Theoretical Studies of Diels-Alder Reaction (Part ). Correlation between the Stabilization Energies of the Transition States and the Resonance Energies of the Isolated Systems [J] . Byung Kak Park, Young Suek Hong Journal of the Korean Chemical Society . 1972,第1期

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Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry

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