Apportionment of Ambient Primary and Secondary Fine Particulate Matter at the Pittsburgh National Energy Laboratory Particulate Matter Characterization Site Using Positive Matrix Factorization and a Potential Source Contributions Function Analysis

摘要

Fine particulate matter (PM_(2.5)) concentrations associated with 202 24-hr samples collected at the National Energy Technology Laboratory (NETL) particulate matter (PM) characterization site in south Pittsburgh from October 1999 through September 2001 were used to apportion PM_(2.5) into primary and secondary contributions using Positive Matrix Factorization (PMF2). Input included the concentrations of PM_(2.5) mass determined with a FederalrnReference Method (FRM) sampler, semi-volatile PM_(2.5) organic material, elemental carbon (EC), and trace element components of PM_(2.5). A total of 11 factors were identified. The results of potential source contributions function (PSCF) analysis using PMF2 factors and HYSPLIT-calculated back-trajectories were used to identify those factors associated with specific meteorological transport conditions. The 11 factors were identified as being associated with emissions from various specific regions and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. Three sources associated with transport from coal-fired power plants to the southeast, a combination of point sources to the northwest, and a steel mill and associated sources to the west were identified. In addition, two secondary-material-dominated sources were identified, one was associated with secondary products of local emissions and one was dominated by secondary ammonium sulfate transported to the NETL site from the west and southwest. Of these 11 factors, the four largest contributors to PM_(2.5) were the secondary transported material (dominated by ammonium sulfate) (47%), local secondary material (19%), diesel combustion emissions (10%), and gasoline combustion emissions (8%). The other seven factors accounted for the remaining 16% of the PM_(2.5) mass. The findings are consistent with the major source of PM_(2.5) in the Pittsburgh area being dominated by ammonium sulfate from distant transport and so decoupled from local activity emitting organic pollutants in the metropolitan area. In contrast, the major local secondary sources are dominated by organic material.