Quantification of emission factor uncertainty

摘要

Emissions, factors are important for estimating and characterizing emissions from sources of air pollution-. There is no quantitative indication of uncertainty for these emission factors, most factors do not have an adequate data set to compute uncertainty, and it is very difficult to locate the data for those that do The objectives are to compare the current emission factors of Electric Generating Unit NO_x sources with currently available continuous emission monitoring data, develop quantitative uncertainty indicators for the Environmental Protection Agency (EPA) data quality rated emission factors, and determine the possible ranges of uncertainty associated with EPA's data quality rating of emission factors. EPA s data letter rating represents a general indication of the robustness of the emission factor and is assigned based on the estimated reliability of the tests used to develop the factor and on the quantity and representativeness of the data. Different sources and pollutants that have the same robustness in the measured emission factor and in the representativeness of the measured values are assumed to have a similar quantifiable uncertainty. For the purposes of comparison, we assume that the emission factor estimates from source categories with the same letter rating have enough robustness and consistency that we can quantify the uncertainty of these common emission factors based on the qualitative indication of data quality which is known for almost all factors. The results showed that EPA's current emission factor values for NO_x emissions from combustion sources were found to be reasonably representative far some sources; however, AP-42 values should be updated for over half of the sources to reflect current data. The quantified uncertainty ranges were found to be 25-62% for A rated emission factors, 45-75% for B rated emission factors, 60-82% for C rated emission factors, and 69-86% for D rated emission factors, and 82-92% for E rated emission factors. Implications: Currently, a letter grade indicates the data quality uncertainty of emission factors in EPA's Compilation of Emission Factors (AP-42). However, a quantitative characterization would be much preferred. If the uncertainty of emission factors is quantified, scientists may be able to more accurately characterize the uncertainty associated with air quality modeling and emission data. A quantitative measure of uncertainty will also give decision makers the ability to determine the confidence that should be placed in the analysis of the data being used for policy decisions.