Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

摘要

The rate constants and the activation parameters of the addition of primary alkyl radicals to allyldibutyl-4,7,10-ntrioxaundecylstannane 1 and (2-ethoxycarbonylprop-2-enyl)dibutyl-4,7,10-trioxaundecylstannane 2 were determinednby studying their respective free radical reactions with (2-bromo-1,1-dimethylethyl)benzene and 6-bromohex-1-ene atndifferent temperatures.