NITRATION OF AROMATIC COMPOUNDS USING ALUMINA SULFURIC ACID(ASA) AS A NOVEL HETEROGENEOUS SYSTEM AND Mg (NO_3)_2·6H_2O AS NITRATING AGENT IN WATER

M. HOSSEINI-SARVARl; M. TAVAKOLIAN; S. ASHENAGAR

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NITRATION OF AROMATIC COMPOUNDS USING ALUMINA SULFURIC ACID(ASA) AS A NOVEL HETEROGENEOUS SYSTEM AND Mg (NO_3)_2·6H_2O AS NITRATING AGENT IN WATER

机译：以铝异氰酸酯为新型异质体系和Mg（NO_3）_2·6H_2O为水中硝酸盐硝化剂的芳族化合物硝化

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摘要

A novel and safe method for nitration of phenols, anilines and other aromatic compounds has been found to be feasible with alumina sulfuric acid (ASA) as catalyst and Mg (NO_3)_2·6H_2O as nitrating agent in neat water as solvent. The use of water makes this method compatible with the green chemistry approach.

机译：发现以硫酸铝（ASA）为催化剂，以Mg（NO_3）_2·6H_2O为硝化剂，在纯水中作为溶剂，硝化酚，苯胺和其他芳族化合物的新方法是可行的。用水使该方法与绿色化学方法兼容。

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来源
《Iranian Journal of Science and Technology》 |2010年第3期|p.215-225|共11页
作者
M. HOSSEINI-SARVARl; M. TAVAKOLIAN; S. ASHENAGAR;
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作者单位

Department of Chemistry, Shiraz University, Shiraz, I. R. of Iran;

Department of Chemistry, Shiraz University, Shiraz, I. R. of Iran;

Department of Chemistry, Shiraz University, Shiraz, I. R. of Iran;

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正文语种 eng
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关键词
alumina sulfuric acid; nitration; mg (no_3)_2·6h_2o; water; heterogeneous;

机译：硫酸铝;硝化;mg（no_3）_2·6h_2o;水;异质;

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专利

1. Supported Bismuth(III)Nitrate on Silica Sulfuric Acid as Useful Reagent for Nitration of Aromatic Compounds under Solvent-Free Conditions* [J] . A.R.Hajipour, A.Zarei, A.E.Ruoho Russian Journal of Organic Chemistry . 2005,第10期

机译：二氧化硅硫酸上负载的硝酸铋（III）作为在无溶剂条件下硝化芳族化合物的有用试剂*
2. Thermodynamic nitration rates of aromatic compounds. Part 4. Temperature dependence in sulfuric acid of HNO3 -> NO2+ equilibrium, nitration rates and acidic properties of the solvent [J] . Marziano NC., Tortato C., Zaldivar JM., Journal of the Chemical Society. Perkin Transactions 2 . 1998,第9期

机译：芳香族化合物的热力学硝化速率。第4部分。HNO3-> NO2 +平衡在硫酸中的温度依赖性，硝化速率和溶剂的酸性
3. Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO _2 in acidic media [J] . Zolfigol M.A., Khazaei A., Moosavi-Zare A.R., The Journal of Organic Chemistry . 2012,第7期

机译：离子液体3-甲基-1-磺酸咪唑鎓硝酸盐在酸性介质中原位生成NO _2作为硝化芳族化合物的试剂的设计
4. Nitration of Aromatic Compounds without Using Sulfuric Acid [C] . Siddharth Parekh, R. N. Shukla, Kamala Vasu 19th Ethylene Producers' Conference Proceedings . 2007

机译：不使用硫酸硝化芳族化合物
5. Extraction of uranium by dibutyl carbitol in the system uranium dioxide(nitrate)(2)-nitric acid-water-calcium(nitrate)(2)-dibutyl carbitol. [D] . Birdwell, Joseph Franklin. 1995

机译：二丁基卡必醇在二氧化铀（硝酸盐）（2）-硝酸-水-硝酸钙（2）-二丁基卡必醇体系中萃取铀。
6. Silica Sulfuric Acid/ NaNO2 as a Novel Heterogeneous System for the Nitration of Phenols under Mild Conditions [O] . Mohammad Ali Zolfigol, Elahe Madrakian, Ezat Ghaemi 2002

机译：二氧化硅硫酸盐/ NaNO2作为温和条件下硝化苯酚的新型异质体系
7. Alumina sulfuric acid (ASA), tungstate sulfuric acid (TSA), molybdate sulfuric acid (MSA) and xanthan sulfuric acid (XSA) as solid and heterogeneous catalysts in green organic synthesis: a review [O] . Rajesh H. Vekariya, Hitesh D. Patel 2014

机译：氧化铝硫酸（asa），钨酸盐（Tsa），钼酸硫酸（msa）和黄原酸硫酸（Xsa）作为绿色有机合成中的固体和非均相催化剂：综述

NITRATION OF AROMATIC COMPOUNDS USING ALUMINA SULFURIC ACID(ASA) AS A NOVEL HETEROGENEOUS SYSTEM AND Mg (NO_3)_2·6H_2O AS NITRATING AGENT IN WATER

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