TEOS-10: A New International Oceanographic Standard for Seawater, Ice, Fluid Water, and Humid Air

摘要

Very accurate empirical thermodynamic potential functions are available for fluid water, ice, seawater, and humid air covering wide ranges of temperature and pressure conditions, including those of the terrestrial hydrosphere and atmosphere. These potential functions are formulated as international standards endorsed by the International Association for the Properties of Water and Steam (IAPWS). A related seawater standard referred to as the International Thermodynamic Equation of Seawater 2010 (TEOS-10) was adopted in 2009 by UNESCO for oceanography. Here, the formulations available from TEOS-10 for the description of the vapor pressure of ice and for thermodynamic properties of humid air, in particular, the relative humidity, are reviewed. It is concluded that the IAPWS formulation for the sublimation pressure is superior in uncertainty and range of validity over other available correlation equations, and that relative fugacity is a physically reasonable generalization of relative humidity for the case of non-ideal gases or equilibria with moist substances.