Studies on improvement of hydrogen storage capacity of AB_5 type:MmNi_(4.6)Fe_(0.4) alloy

摘要

This paper deals with enhancement of hydrogen storage capacity for AB_5 type alloy MmNi_(4.6)Fe_(0.4) from ～1.5 to ～2.04 wt%. It has been shown that through suitable processing involving ball milling with specific parameters (200 rpm, 20 min), the alloy particles besides getting fractured to smaller particles also become strained. The maximum strain, increase in lattice constant and unit cell volume are achieved for ball milling parameters of ～200 rpm and 20 min. It has been suggested that the increase in the unit cell volume results in increase of interstitial hole sizes. This induces higher number of interstitials in unit cell of the material MmNi_(4.6)Fe_(0.4) to be occupied by hydrogen atoms resulting in increase of hydrogen storage capacity from its value of ～1.5 wt% obtained in the as-synthesized material to ～2.04 wt% for ball-milled materials which embody strained particles.