Study of the miscibility gap in H_2SO_4/HI/I_2/H_2O mixtures produced by the Bunsen reaction - Part I: Preliminary results at 308 K

摘要

In the framework of the optimization of the sulfur-iodine thermochemical cycle for massive hydrogen production, investigations were performed in order to characterize the liquid phase (HIx and H_2SO_(4(aq)) phases) separation of solutions resulting from Bunsen reaction. Quaternary H_2SO_4/HI/I_2/H_2O mixtures were prepared at 308 K with different relative proportions of reactants and the chemical composition of each of the two phases formed was analyzed. An increase in iodine concentration and a decrease in water concentration appeared to improve the liquid-liquid equilibrium phase separation. However, a too low concentration of water also promoted the formation of byproducts. An increase in the [H_2SO_4]/[HI] ratio tended to favor the separation and seemed to lead to a dehydration of the HIx phase.