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Combustion of hydrogen-air in catalytic micro-combustors made of different material

机译:氢气-空气在不同材料制成的催化微型燃烧器中的燃烧

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摘要

Micro-combustors have low stability, thus catalyst is applied to improve it. In this experiment, the performances of catalytic micro-combustors made of different materials (quartz glass, alumina ceramic, copper) are compared. Asbestine threads are used as the catalyst supports of Pt, and installed in the combustors. According to the experimental results, the combustors have high stability, they keep working until the extreme equivalence ratio close to 0. The stability limits of homogeneous reaction in the quartz glass and alumina ceramic combustor range from 0.0907 to 8.69 and 0.158 to 7.31 on average, respectively. But the two combustors exhibit obvious hot spots, which are 1058 and 728 K at 0.2 L/min, respectively. Whereas the copper combustor has low and uniform temperature distribution on its surface. Moreover, the heat loss in the quartz glass combustor is 4.13 W higher than in the copper one at 0.2 L/min, which is opposite to the conventional situation that heat loss increases with the wall thermal rnconductivity. Computational fluid dynamic simulation reveals that the reaction modes inside the combustors differ. The higher wall thermal conductivity makes the heterogeneous reaction dominate, thus induces the temperature distribution and heat loss aforementioned.
机译:微型燃烧器具有低稳定性,因此使用催化剂对其进行改进。在该实验中,比较了由不同材料(石英玻璃,氧化铝陶瓷,铜)制成的催化微燃烧器的性能。石棉线用作Pt的催化剂载体,并安装在燃烧室中。根据实验结果,燃烧器具有很高的稳定性,它们可以一直工作到极限当量比接近0为止。石英玻璃和氧化铝陶瓷燃烧器中均相反应的稳定极限范围为0.0907至8.69和0.158至7.31,分别。但是,两个燃烧器都显示出明显的热点,在0.2 L / min时分别为1058和728K。而铜燃烧器在其表面上具有较低且均匀的温度分布。此外,石英玻璃燃烧室中的热损失为0.2 L / min,比铜制燃烧室的热损失高4.13 W,这与传统的情况相反,即热损失随着壁的导热性增加而增加。计算流体动力学模拟表明,燃烧室内部的反应模式不同。较高的壁导热率使非均相反应占优势,从而引起上述温度分布和热损失。

著录项

  • 来源
    《International journal of hydrogen energy》 |2009年第8期|3535-3545|共11页
  • 作者单位

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

    State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    micro-combustor; catalyst; hydrogen; material; thermal conductivity;

    机译:微型燃烧器催化剂;氢;材料;导热系数;
  • 入库时间 2022-08-18 00:29:52

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