Fabrication of nickel boride-coated carbon nanotube films by electrophoresis and electroless deposition for electrochemical hydrogen storage

摘要

Network-like carbon nanotube (CNT) films free of polymer binder were deposited directly onto a stainless steel substrate by electrophoresis. Results of experiments indicated that a CNT film with duplex surface treatment (nitric acid etching and nickel boride coating) provides satisfactory electrochemical hydrogen storage. Nitric acid treatment increased the hydrogen storage capacity of the CNT film due to the opening of CNTs, the formation of micropores in the CNT surface, and the improvement of surface wettability. Coating the CNT film with nickel boride (Ni2B) greatly improved the electrochemical activity of the film and consequently increased the hydrogen storage capacity. The optimal amount of nickel boride coating on the CNT film was found to be about 45 wt%. Smaller amounts of nickel boride cannot provide enough electrochemical activity. Excessive nickel boride, on the other hand, leads to a decrease in the number of active sites on CNTs that are available for hydrogen storage.