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首页> 外文期刊>International journal of hydrogen energy >Corrosion resistance and interfacial contact resistance of TiN coated 316L bipolar plates for proton exchange membrane fuel cell
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Corrosion resistance and interfacial contact resistance of TiN coated 316L bipolar plates for proton exchange membrane fuel cell

机译:质子交换膜燃料电池用TiN涂层316L双极板的耐蚀性和界面接触电阻

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摘要

TiN coating is successfully deposited on 316L by multi-arc ion plating. Corrosion behavior of TiN coated 316L is studied in 0.05 M H_2SO_4 + 2 ppm F~- simulating proton exchange membrane fuel cell (PEMFC) environments using electrochemical method, and interfacial contact resistance (ICR) is measured before and after potentiostatic polarization at operation potential for PEMFC. The TiN coated 316L exhibits promising ICR and improved corrosion resistance in simulated aggressive PEMFC environments. Only general overall corrosion is observed after potentiostatic polarization. Stable passive film has formed on the surface of the TiN coated 316L after potentiostatic polarization at the operation potential and results in a slight increase in the ICR. These results indicate that the TiN coated 316L is a candidate bipolar plate material for PEMFC stacks.
机译:TiN涂层通过多弧离子镀成功沉积在316L上。研究了TiN涂层316L在0.05 M H_2SO_4 + 2 ppm F〜下的腐蚀行为,采用电化学方法模拟质子交换膜燃料电池(PEMFC),并在恒电位极化之前和之后测量了界面接触电阻(ICR)。 PEMFC。 TiN涂层316L在模拟侵蚀性PEMFC环境中展现出可观的ICR和改善的耐腐蚀性。恒电位极化后仅观察到总体腐蚀。恒电位极化后,在工作电位下,TiN涂层316L的表面形成了稳定的无源膜,导致ICR略有增加。这些结果表明,TiN涂层316L是PEMFC叠层的候选双极板材料。

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