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Methanol-tolerant carbon aerogel-supported Pt-Au catalysts for direct methanol fuel cell

机译:直接甲醇燃料电池的耐甲醇碳气凝胶负载Pt-Au催化剂

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摘要

Pt-Au nanoparticles supported on carbon aerogel, namely 2:1 has been synthesized by the microwave-assisted polyol process. The structure of Pt-Au nanoparticles is characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The electrochemical property of Pt-Au catalysts for methanol oxidation is evaluated by cyclic vol-tammetry (CV). The results show that Au-modified Pt catalysts exhibit a high methanol tolerance and improved electrochemical catalytic activity, suggesting that carbon aerogel supported Pt-Au catalysts are better catalysts for the electrochemical oxidation of methanol than conventional Pt catalysts.
机译:通过微波辅助多元醇法合成了负载在碳气凝胶上的Pt-Au纳米颗粒,即2:1。 Pt-Au纳米颗粒的结构通过透射电子显微镜(TEM)和X射线衍射(XRD)表征。通过循环伏安法(CV)评估Pt-Au催化剂氧化甲醇的电化学性能。结果表明,Au改性的Pt催化剂具有较高的甲醇耐受性和改善的电化学催化活性,表明碳气凝胶负载的Pt-Au催化剂比常规的Pt催化剂更适合甲醇的电化学氧化。

著录项

  • 来源
    《International journal of hydrogen energy》 |2012年第1期|p.873-876|共4页
  • 作者单位

    Institute of Modern Catalyst, State Key Laboratory of Chemical Resource Engineering, School of Science, Department of Chemistry,Beijing University of Chemical Technology, Beijing 100029, China;

    Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing 100044, China;

    Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing 100044, China;

    Institute of Modern Catalyst, State Key Laboratory of Chemical Resource Engineering, School of Science, Department of Chemistry,Beijing University of Chemical Technology, Beijing 100029, China;

    Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing 100044, China;

    Institute of Modern Catalyst, State Key Laboratory of Chemical Resource Engineering, School of Science, Department of Chemistry,Beijing University of Chemical Technology, Beijing 100029, China;

    Institute of Modern Catalyst, State Key Laboratory of Chemical Resource Engineering, School of Science, Department of Chemistry,Beijing University of Chemical Technology, Beijing 100029, China;

    Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing 100044, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Pt-Au; carbon aerogel; microwave-assisted polyol process; electrocatalyst; direct methanol fuel cell;

    机译:铂金碳气凝胶微波辅助多元醇工艺;电催化剂直接甲醇燃料电池;
  • 入库时间 2022-08-18 00:28:17

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