Comparison of alkaline stability of benzyltrimethylammonium, benzylmethylimidazolium and benzyldimethylimidazolium functionalized poly(arylene ether ketone) anion exchange membranes

摘要

The alkaline stability of benzyltrimethylammonium, benzylmethylimidazolium and benzyldimethylimidazolium functionalized poly(arylene ether ketone) anion exchange membranes (AEMs) were investigated by conductivity change and NMR experiments. The corresponding small molecular model compounds were synthesized and used to determine the degradation degree of benzyltrimethylammonium, benzylmethylimidazolium and benzyldimethylimidazolium cations. The results showed only 7% of benzyltrimethylammonium model compound degraded in 1 M NaOH at 60 degrees C; whereas, benzylmethylimidazolium and benzyldimethylimidazolium model compounds had a degradation of 55% and 46% at the same condition, respectively. The alkaline stability of three cations follows the order: benzyltrimethylammonium > benzyldimethylimidazolium > benzylmethylimidazolium, The NMR spectra and hydroxide conductivity change with immersing time in 1 M NaOH at 60 degrees C also confirmed that benzyltrimethylammonium functionalized polymer had a relative better alkaline stability than benzylmethylimidazolium and benzyldimethylimidazolium functionalized polymers in alkaline environment at elevated temperature. This research enriches the investigation on the alkaline stability of anion exchange membranes with quatemary ammonium, imidazolium and C2-substituted imidazolium. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.