Alkaline anion exchange membrane degradation as a function of humidity measured using the quartz crystal microbalance

摘要

The solid polymer electrolyte (SPE) alkaline anion exchange membrane (AAEM) fuel cell exhibits facile oxygen reduction reaction (ORR) kinetics and has the ability to utilise non precious metal electrocatalysts. However, the AAEM is reported to suffer from increased instability within the alkaline media (degradation) via a number of routes, including nucleophilic elimination when operated at temperatures above 60 degrees C, somewhat eliminating the kinetic advantage of operating at higher temperatures. Nonetheless, modelling studies have indicated that the membrane hydration could show improved resistance to alkaline instability and subsequent degradation when operated at elevated temperatures. This investigation uses the quartz crystal microbalance (QCM) to examine the thermal stability of a commercial AAEM as a function of humidity. The results show that hydration improves ionomer resistance to degradation, as the ions within the system (namely the OH- nucleophile and cationic headgroups) become less reactive. In-line mass spectrometry data confirms that the ionomer degrades during the elevated temperature excursions used in this study. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.