Compaction of LiBH4-LiAlH4 nanoconfined in activated carbon nanofibers: Dehydrogenation kinetics, reversibility, and mechanical stability during cycling

摘要

To enhance volumetric hydrogen capacity for on-board fuel cells, compaction of LiAlH4-LiBH4 nanoconfined in activated carbon nanofibers (ACNF) is for the first time proposed. Loose powders of milled and nanoconfined LiAlH4-LiBH4 samples are compacted under 976 MPa to obtain the pellet samples with thickness and diameter of similar to 1.20-1.30 and 8.0 mm, respectively. Dehydrogenation temperature of milled LiAlH4-LiBH4 increases from 415 to 434 degrees C due to compaction, while those of both compacted and loose powder samples of nanoconfined LiAlH4-LiBH4 are lower at comparable temperature of 330-335 degrees C. Hydrogen content liberated from milled LiAIH4-LiBH4 pellet is 65% of theoretical capacity in the temperature range of 80 -475 degrees C, while that of nanoconfined LiAlH4-LiBH4 pellet is up to 80% atlower temperature of 100 -400 degrees C. Besides, nanoconfined LiAlH4-LiBH4 pellet shows significant reduction of activation energy (Delta E-A up to 69 kJ/mol H-2) as compared with milled sample. Significant enhancement of volumetric hydrogen storage capacity up to 64% (from 32.5 to 53.3 gH(2)/L) is obtained from nanoconfined LiAlH4-LiBH4 pellet. Hydrogen content released and reproduced of nanoconfined LiAlH4-LiBH4 pellet are 67 and 50% of theoretical capacity, respectively, while those of milled LiAlH4-LiBH4 pellet are only 30 and 10%, respectively. Moreover, upon four hydrogen release and uptake cycles, nanoconfined LiAlH4-LiBH4 pellet can preserve its shape with slight cracks, suggesting good mechanical stability during cycling. Curvatures and fibrous structure woven on one another of ACNF in nanoconfined LiAlH4-LiBH4 pellet not only favor hydrogen permeability through pellet sample during de/rehydrogenation, resulting fast kinetics, but also reinforce the pellet shape during cycling under high temperature and pressure condition. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.