Design and performance analysis of a de-coupled solid oxide fuel cell gas turbine hybrid

摘要

Hybrid solid oxide fuel cells (SOFC) cycles of varying complexity are widely studied for their potential efficiency, carbon recovery and co-production of chemicals. This study introduces an alternative de-coupled fuel cell-gas turbine hybrid arrangement that retains the high efficiency thermal integration of a topping cycle without the high temperature heat exchanger of a bottoming cycle. The system utilizes a solid-state oxygen transport membrane to divert 30%-50% of the oxygen from the turbine working fluid to the intermediate temperature SOFC. Thermodynamic modeling delineates design trade-offs and identifies a flexible operating regime with peak fuel-to-electric efficiency of 75%. Co-production of electricity and high purity hydrogen result in net energy conversion efficiencies greater than 80%. The potential to retrofit existing turbine systems, particularly micro-turbines and stand-by `pecker' plants, with minimal impact to compressor stability or transient response is a promising pathway to hybrid fuel cell/turbine development that does not require turbomachinery modification. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.