Small hydrogen storage tank filled with 2LiBH_4-MgH_2 nanoconfined in activated carbon: Reaction mechanisms and performances

摘要

De/rehydrogenation performances and reaction pathways of nanoconfined 2LiBH(4)-MgH2 into activated carbon (AC) packed in small hydrogen storage tank are proposed for the first time. Total and material storage capacities upon five hydrogen release and uptake cycles are 3.56-4.55 and 2.03-3.28 wt % H-2, respectively. Inferior hydrogen content to theoretical capacity (material capacity of 5.7 wt % H-2) is due to partial dehydrogenation during sample preparation and incomplete decomposition of LiBH4 as well as the formation of thermally stable Li2B22H12 upon cycling. Two-step dehydrogenation of MgH2 and LiBH4 to produce Mg and MgB2+LiH, respectively is found at all positions in the tank. For rehydrogenation, reversibility of MgH2 and LiBH4 proceeds via different reaction mechanisms. Although isothermal condition (T-set = 350 degrees C) and controlled pressure range (e.g., 30-40 bar H-2 for hydrogenation) are applied, temperature gradient inside the tank and poor hydrogen diffusion through hydride bed, especially in the sample bulk are detected. This results in alteration of de/rehydrogenation pathways of hydrides at different positions in the tank. Thus, further development of hydrogen storage tank based 2LiBH(4)-MgH2 nanoconfined in AC includes the improvement of thermal conductivity of materials and temperature control system as well as hydrogen permeability. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.