Numerical and experimental study on silica generating counterflow diffusion flames

摘要

Temperatures and concentrations of OH radicals in silica generating counterflow oxy-hydrogen diffusion flames are measured using a broadband coherent anti-Stokes Raman spectroscopy (CARS) and a planar laser induced fluorescence (PLIF) techniques to study thermo-chemical effects of SiCl_4 addition to flames. Numerical analysis considering detailed chemical reactions including silica generating reactions is also conducted. The experimental results demonstrate that temperatures decrease in preheated zone due to the increase in specific heat of the gas mixture while the decrease is mitigated in particle formation zone due to the heat release through hydrolysis and oxidation reactions of SiCl_4. Also, OH concentrations significantly decrease in silica formation flame, which can be attributed to the consumption of oxi-dative radicals during the silica generating reactions of SiCl_4 and depletion of OH by HCl. The numerical simulation agrees well for flames having relatively low flame temperatures of 1750K but underestimates the decrease in OH concentration for high temperature flame over 2700 K. The disagreement for the high temperature flames would imply possible OH consumption via direct reactions between OH radicals and silicon chlorides, which is expected to be highly sensitive to temperature.