Effective thermal conductivity modeling of hollow nanosphere packing structures

摘要

Nanoporous insulating materials are of importance for applications such as energy-efficient buildings, energy storage and savings, and cryogenic engineering. Recent progress on manufacturing technology has enabled the fabrication of ordered nanostructures to be practical, providing a possibility to fabricate high-performance insulation materials. In this work, three kinds of nanoporous insulating materials with regular geometric structures and controllable thermal conductivities, including a simple cubic packing, a face-centered cubic packing, and a cubic array of intersecting spheres packing of uniform-sized hollow nanospheres, were designed. The effective thermal conductivity models of each packing structure were developed according to the assumption of one-dimensional heat transfer, in which the following factors including material types, size of the hollow nanosphere packing structure (e.g., sphere size, spherical shell thickness, contact ratio), gas pressure, the rarefaction effect of gas and the mean free path of phonons were considered. The developed models of the hollow nanosphere packing structures were validated by the experimental results from the literature. It is found that the effective thermal conductivity can be loweted to ～ 0.01 W/(mK) by tuning the packing style and size of hollow nanosphere packing structures in the room environment, showing excellent thermal insulation performance. The work provides a new strategy for the design of super-insulation materials.