Numerical analysis of the single electrode heat effect in molten carbonate fuel cells: temperature analysis of the electrolyte plate by applying irreversible thermodynamics

摘要

A temperature analysis model of a molten carbonate fuel cells (MCFC) stack is used to calculate the single electrode heat effects. The magnitude of heat which evolves from the cathode and absorbed at the anode is large, and in similar value to the electrical output of a MCFC. This suggests that the heat evolution of a single electrode causes a temperature difference between the electrodes. The temperature distribution in the electrolyte plate is evaluated to establish more accurate results concerning the temperature analysis model of the stack. The temperature distribution in the electrolyte plate is studied by applying irreversible thermodynamics. When the operating current density is less than 3000 A m{sup}(-2) and the thermal conductivity of the electrolyte is more than 2Wm{sup}(-1)K{sup}(-1), the temperature difference between cathode and anode is estimated to be less than approximately 1K. This result proves that the temperature difference between the electrodes can be supposed constant in constructing the temperature analysis model of the MCFC stack. This results also allows us to construct a two-dimensional heat production distribution in the cell plane and discrete heat production distribution in the stacking direction for the practical use of the temperature analysis model.