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Metal-Containing Nanocomposites on the Basis of Isotactic Polypropylene

机译:基于全同立构聚丙烯的含金属纳米复合材料

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摘要

The influence of additions of nanofillers (NF) containing nanoparticles of copper oxide stabilized by a polymer matrix of polyethylene of high pressure, prepared by a mechanochemical method, on peculiarities of the structure and properties of mixed thermoplastic elastomers on the basis of isotactic polypropylene (PP) and ethylene propylene elastomer of double (EPM) and triple (EPDM) by the methods of X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermographical (TGA) analyses has been investigated. It has been shown that an introduction of metal-containing NF in PP/EPDM leads to the formation of fine-spherulitic structure of the filled composition and thereby to improvement of fluidity and thermal-oxidative stability, and in the case of PP/EPM, the physicomechanical properties are improved, and the composition does not flow. Mixture of TPE on the basis of PP/EPM/NF can be processed only by the method of pressing and on the basis of PP/EPDM/NF both by the method of pressing and by the methods of casting under pressure and extrusion, which expands the sphere of its application.
机译:机械化学方法制得的通过高压聚乙烯的聚合物基体稳定的,含有氧化铜纳米粒子的纳米填料(NF)的添加对基于全同立构聚丙烯(PP)的混合热塑性弹性体的结构和性能的特性的影响)以及通过X射线衍射(XRD),扫描电子显微镜(SEM)和热成像(TGA)分析的方法研究了双(EPM)和三重(EPDM)的乙烯丙烯弹性体。已经表明在PP / EPDM中引入含金属的NF导致填充的组合物的细球状结构的形成,从而导致流动性和热氧化稳定性的改善,并且在PP / EPM的情况下,物理机械性能得到改善,并且该组合物不流动。在PP / EPM / NF基础上的TPE混合物只能通过压制方法进行加工,而在PP / EPDM / NF基础上既可以通过压制方法进行加工,也可以通过在压力和挤压下进行浇铸的方法进行加工,从而扩大了其应用范围。

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